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Optimising the oil phases of aluminium hydrogel-stabilised emulsions for stable, safe and efficient vaccine adjuvant

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 973-984 doi: 10.1007/s11705-021-2123-1

摘要： To increase antibody secretion and dose sparing, squalene-in-water aluminium hydrogel (alum)-stabilised emulsions (ASEs) have been developed, which offer increased surface areas and cellular interactions for higher antigen loading and enhanced immune responses. Nevertheless, the squalene (oil) in previous attempts suffered from limited oxidation resistance, thus, safety and stability were compromised. From a clinical translational perspective, it is imperative to screen the optimal oils for enhanced emulsion adjuvants. Here, because of the varying oleic to linoleic acid ratio, soybean oil, peanut oil, and olive oil were utilised as oil phases in the preparation of aluminium hydrogel-stabilised squalene-in-water emulsions, which were then screened for their stability and immunogenicity. Additionally, the underlying mechanisms of oil phases and emulsion stability were unravelled, which showed that a higher oleic to linoleic acid ratio increased anti-oxidative capabilities but reduced the long-term storage stability owing to the relatively low zeta potential of the prepared droplets. As a result, compared with squalene-in-water ASEs, soybean-in-water ASEs exhibited comparable immune responses and enhanced stability. By optimising the oil phase of the emulsion adjuvants, this work may offer an alternative strategy for safe, stable, and effective emulsion adjuvants.

关键词： pickering emulsion     vaccine adjuvant     alum-stabilised emulsion     oleic to linoleic acid ratio     stability    

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Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production

《化学科学与工程前沿（英文）》 2022年 第16卷 第8期   页码 1198-1210 doi: 10.1007/s11705-021-2133-z

摘要： Sulfonic acid functionalized mesoporous silica based solid acid catalysts with different morphology were designed and fabricated. The synthesized materials were characterized by various physicochemical and spectroscopic techniques like scanning electron microscope-energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, Brunauer–Emmett–Teller surface area, thermogravimetric analysis and n-butylamine acidity. The shape of catalysts particles plays an important role in its activity. The sulfonic acid functionalized mesoporous silica catalysts of spherical shape and the cube shape were assessed for catalytic activity in biodiesel production. The catalytic biodiesel production reaction over the catalysts were studied by esterification of free fatty acid, oleic acid with methanol. The effect of various reaction parameters such as catalyst concentration, acid/alcohol molar ratio, catalyst amount, reaction temperature and reaction time on catalytic activity were investigated to optimize the conditions for maximum conversion. It was sulfonated cubic shape mesoporous silica which exhibited better activity as compared to the spherical shape silica catalysts. Additionally, the catalyst was regenerated and reused up to three cycles without any significant loss in activity. The present catalysts exhibit superior performance in biodiesel production and it can be used for the several biodiesel feedstock’s that are rich in free fatty acids.

关键词： solid acid catalyst     mesoporous silica     sulfonic acid     biodiesel     esterification     oleic acid    

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The influence of the NCO/OH ratio and the 1,6-hexanediol/dimethylol propionic acid molar ratio on the

Jiao Feng, Qiuhao Lu, Weimin Tan, Kequan Chen, Pingkai Ouyang

《化学科学与工程前沿（英文）》 2019年 第13卷 第1期   页码 80-89 doi: 10.1007/s11705-018-1763-2

摘要：

1,5-Pentamethylene diisocyanate, a novel aliphatic diisocyanate formed from bio-based 1,5-pentamethylenediamine, has been used as a hard segmented material to synthesize polyurethane. In this study, several waterborne polyurethane (WPU) dispersions have been successfully prepared by a prepolymer process from 1,5-pentamethylene diisocyanate poly(polyether) with different NCO/OH ratios and 1,6-hexanediol (HDO)/dimethylol propionic acid (DMPA) molar ratios. The Fourier transform infrared (FTIR) spectra, thermogravimetric analysis, differential scanning calorimetry, X-ray diffraction, and a mechanical tensile test were used to investigate the structures, thermal stability, phase separation, crystallinity, mechanical properties, and adhesive performance of the WPU dispersions. The FTIR results indicate that the degree of hydrogen bonding and the numbers of urea groups increase as the NCO/OH ratio and HDO/DMPA molar ratio increase. Furthermore, the phase separation increases and the thermal stability decreases as the NCO/OH ratio increases or the HDO/DMPA molar ratio decreases. Finally, WPU3.0-2.4 (NCO/OH=3, HDO/DMPA=2.4) exhibits a maximum tensile strength and shear strength, pointing to its possible use as an adhesive. These results could provide a very valuable reference for industrial applications of WPU.

关键词： 1     5-pentamethylene diisocyanate     polyurethane     water based    

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Concentrating aqueous hydrochloric acid by multiple-effect membrane distillation

Rongling LIU, Yingjie QIN, Xiaojun LI, Liqiang LIU

《化学科学与工程前沿（英文）》 2012年 第6卷 第3期   页码 311-321 doi: 10.1007/s11705-012-1207-3

摘要： Multiple-effect membrane distillation (MEMD) using a hollow fiber-based air-gap membrane distillation module was experimentally examined for concentrating dilute aqueous hydrochloric acid. The effects of the hot and cold feed-in temperatures, and the feed-in volumetric flow rates on the performance of the MEMD process were studied. The performance was evaluated using the performance ratio ( ), the average selectivity of water over HCl ( ) and the permeation flux ( ). Two types of porous fibers made from polypropylene were used to fabricate the MEMD modules. The experimental data indicated that hollow fibers with high porosity were preferred for the MEMD process. The , and all decreased as the feed concentration increased. When the feed concentration was below 12 wt-%, the was 6.0 – 9.6 and was 10 – 190. When the concentration of HCl reached 18 wt-%, the and were about 4.4 and 2.3, respectively. However, sharply decreased to around 1.0 when the feed was further concentrated. During an operational stability test that lasted for 30 days, the performance of the MEMD modules remained good.

关键词： multiple-effect membrane distillation     performance ratio     hydrochloric acid     recovery     stability    

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高油酸油菜中甘油三酯的组成及结构研究 Artical

官梅,陈洪,熊兴华,吕昕,李栒,黄凤洪,官春云

《工程（英文）》 2016年 第2卷 第2期   页码 258-262 doi: 10.1016/J.ENG.2016.02.004

摘要：

植物油中甘油三酯(TAG)的脂肪酸组成及其在甘油主链上的位置决定了植物油脂的营养价值。本研究采用气相色谱法(GC)和高效液相色谱– 串联质谱联用(HPLC-MS/MS)分析了不同油酸含量的甘蓝型油菜籽油的甘油三酯的脂肪酸组成和结构。结果表明：高油酸油菜籽油的油酸含量为80%左右。TAG酰基总碳数(CN值)为54的甘油三酯的相对含量占80%以上。主要的甘油三酯为OOO，相对含量最高达71.75%，其次是OOL 7.56%、OOLn 4.81%和SOO 4.74%。在高油酸的品种中油酸主要集中在甘油三酯上的sn-2位，而在高芥酸品种中，油酸主要集中在甘油三酯上的sn-1/3位置。结果表明，高油酸油菜籽油是一种具有极高营养价值的植物油。

关键词： 油菜     脂肪酸     甘油三酯     位置异构体    

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油压极值比与极值比效率

齐茂林

《中国工程科学》 2001年 第3卷 第4期   页码 73-75

摘要：

文章应用基础公式，推导液压系统油压极值比与极值比效率之间的关系式。该式说明，油压极值比越大，极值比效率就越低。提出了油压极值比是可以设计和选择的。

关键词： 油压极值比     极值比效率     液压系统    

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Controlling interstory drift ratio profiles via topology optimization strategies

《结构与土木工程前沿（英文）》 2023年 第17卷 第2期   页码 165-178 doi: 10.1007/s11709-022-0892-3

摘要： An approach to control the profiles of interstory drift ratios along the height of building structures via topology optimization is proposed herein. The theoretical foundation of the proposed approach involves solving a min–max optimization problem to suppress the maximum interstory drift ratio among all stories. Two formulations are suggested: one inherits the bound formulation and the other utilizes a p-norm function to aggregate all individual interstory drift ratios. The proposed methodology can shape the interstory drift ratio profiles into inverted triangular or quadratic patterns because it realizes profile control using a group of shape weight coefficients. The proposed formulations are validated via a series of numerical examples. The disparity between the two formulations is clear. The optimization results show the optimal structural features for controlling the interstory drift ratios under different requirements.

关键词： interstory drift ratio     aggregation function     bound formulation     min–max problem     topology optimization    

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A methodology of implementing target mixing ratio for asphalt mixture

Yucheng HUANG, Lun JI, Rui WEN, Ming ZHANG

《结构与土木工程前沿（英文）》 2017年 第11卷 第3期   页码 308-314 doi: 10.1007/s11709-017-0405-y

摘要： In order to implement the objective mix design of hot mix asphalt adequately during the construction process, the significance of objective mixing ratio was elaborated, and the variability of materials and its control method were analyzed. An engineering example is used to illustrate the debugging process of asphalt mixture batching & mixing plant and the dynamic quality management methods. The results show that the set of methods can not only implement the objective mixing ratio of hot mix asphalt adequately, but also control production during the construction process effectively.

关键词： asphalt mixture     target mixing ratio     mix design implementation     batching & mixing plant debugging    

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Diagnostic evaluation of plasma aldosterone concentration to plasma renin activity ratio in primary aldosteronism

ZHANG Huilan, WANG Daowen

《医学前沿（英文）》 2008年 第2卷 第1期   页码 11-14 doi: 10.1007/s11684-008-0003-4

摘要： Using the plasma aldosterone concentration to plasma renin activity ratio (PAC/PRA ratio) as the screening test of choice for primary aldosteronism in hypertensive patients, we studied the clinical characteristics and the diagnostic value of PAC/PRA ratio in primary aldosteronism. The plasma aldosterone concentration (PAC) and plasma renin activity (PRA) levels were measured by radioimmunoassay in 902 hypertensive patients from out-patient clinics or hospitals. One hundred and twenty-six suspected primary aldosteronism patients whose PAC/PRA ratio was > 25 ng/dL/ng/mL/hr had a lamellar computed tomography (CT) scan in the adrenal gland and follow-up visits. The proportion of primary aldosteronism in hypertensive patients was 14% (126/902). There were 54 patients with unilateral or bilateral hyperplasia and 25 patients with adenoma according to the CT scan. 39% (49/126) of the patients with primary aldosteronism had hypokalemia. Twenty-five patients received surgical treatment. The efficacy and cure rates were 100% (25/25) and 48% (12/25), respectively. The effective rate of aldactone and the single-drug cure rate were 89% (48/54) and 24% (13/54), respectively. Primary aldosteronism affects over 10% of hypertensive patients in China. The PAC/PRA ratio can be considered as a routine screening test in hypertensives, especially resistant hypertensive patients and a high PAC/PRA ratio is an invaluable index in primary aldosteronism diagnosis.
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Enhancing the efficiency of nitrogen removing bacterial population to a wide range of C:N ratio (1.5:

《环境科学与工程前沿（英文）》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1522-y

摘要：

• Simultaneous C & N removal in Methammox occurs at wide C:N ratio.

关键词： Methanogens     Biological Nitrogen Removal (BNR)     Simultaneous     Methammox     C:N ratio    

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Experimental study of structural damage identification based on modal parameters and decay ratio of acceleration

Zhigen WU, Guohua LIU, Zihua ZHANG

《结构与土木工程前沿（英文）》 2011年 第5卷 第1期   页码 112-120 doi: 10.1007/s11709-010-0069-3

摘要： A novel damage assessment method based on the decay ratio of acceleration signals (DRAS) was proposed. Two experimental tests were used to show the efficiency. Three beams were gradually damaged, and then the changes of dynamic parameters were monitored from initial to failure state. In addition, a new method was compared with the linear modal-based damage assessment using wavelet transform (WT). The results clearly show that DRAS increases in linear elasticity state and microcrack propagation state, while DRAS decreases in macrocrack propagation state. Preliminary analysis was developed considering the beat phenomenon in the nonlinear state to explain the turn point of DRAS. With better sensibility of damage than modal parameters, probably DRAS is a promising damage indicator in damage assessment.

关键词： damage assessment     decay ratio of acceleration signals (DRAS)     wavelet transform (WT)     modal analysis     reinforced concrete beam     beat phenomenon    

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Amino acid promoted hydrogen battery system using Mn-pincer complex for reversible CO hydrogenation toformic acid

《能源前沿（英文）》 2022年 第16卷 第5期   页码 697-699 doi: 10.1007/s11708-022-0843-7

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Long term performance of recycled concrete beams with different water–cement ratio and recycled aggregate

Jingwei YING; Feiming SU; Shuangren CHEN

《结构与土木工程前沿（英文）》 2022年 第16卷 第3期   页码 302-315 doi: 10.1007/s11709-022-0803-7

摘要： The purpose of this study is to reveal the service performance of recycled aggregate concrete (RAC) components for different values of water−cement ratio and replacement rate of recycled coarse aggregate (RCA). Generally, the concrete strength decreases with the increase of the replacement rate of RCA, in order to meet the strength requirements when changing the replacement rate of RCA, it is necessary to change the water−cement ratio at the same time. Therefore, the axial compressive strengths of prism with 25 mix proportions, the short-term mechanical properties and long-term deformation properties of reinforced concrete beams were tested respectively by changing water−cement ratio and RCA replacement rate. The bearing capacity and the strain nephogram of samples under different loads were obtained using the Digital Image Correlation (DIC) method, and a self-made gravity loading experimental device was used for long-term deformation investigation. Results showed that the damage pattern of RAC was the same as that of natural aggregate concrete (NAC), but the brittleness was more pronounced. The brittleness of concrete before failure can be reduced more effectively by adjusting the replacement rate of RCA than by adjusting the water−cement ratio. The water−cement ratio has an evident influence on the axial compressive strength and early creep of concrete, while the replacement rate of RCA has a remarkable effect on the long-term deformation of the concrete beams.

关键词： recycled concrete     beam     the replacement rate of recycled coarse aggregate     water–cement ratio     digital image correlation    

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Influence of nozzle height to width ratio on ignition and NO

Liutao SUN, Yonghong YAN, Rui SUN, Zhengkang PENG, Chunli XING, Jiangquan WU

《能源前沿（英文）》 2021年 第15卷 第2期   页码 431-448 doi: 10.1007/s11708-021-0726-3

摘要： To improve the ignition behavior and to reduce the high NO emissions of blended pulverized fuels (PF) of semicoke (SC), large-scale experiments were conducted in a 300 kW fired furnace at various nozzle settings, i.e., ratios (denoted by / ) of the height of the rectangular burner nozzle to its width of 1.65, 2.32, and 3.22. The combustion tests indicate that the flame stability, ignition performance, and fuel burnout ratio were significantly improved at a nozzle setting of / = 2.32. The smaller / delayed ignition and caused the flame to concentrate excessively on the axis of the furnace, while the larger / easily caused the deflection of the pulverized coal flame, and a high-temperature flame zone emerged close to the furnace wall. NO emissions at the outlet of the primary zone decreased from 447 to 354 mg/m (O = 6%), and the ignition distance decreased from 420 to 246 mm when the / varied from 1.65 to 3.22. Furthermore, the ratio (denoted by / ) of the strong reduction zone area to the combustion reaction zone area was defined experimentally by the CO concentration to evaluate the reduction zone. The / rose monotonously, but its restraining effects on NO formation decreased as / increased. The results suggested that in a test furnace, regulating the nozzle / conditions sharply reduces NO emissions and improves the combustion efficiency of SC blends possessing an appropriate jet rigidity.

关键词： rectangular jet burner     nozzle height to width ratio     ignition characteristics     pyrolyzed semicoke (SC) and bituminous blend     NOx formation    

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Enzyme@bismuth-ellagic acid: a versatile platform for enzyme immobilization with enhanced acid-base stability

《化学科学与工程前沿（英文）》 2023年 第17卷 第6期   页码 784-794 doi: 10.1007/s11705-022-2278-4

摘要： In situ encapsulation is an effective way to synthesize enzyme@metal–organic framework biocatalysts; however, it is limited by the conditions of metal–organic framework synthesis and its acid-base stability. Herein, a biocatalytic platform with improved acid-base stability was constructed via a one-pot method using bismuth-ellagic acid as the carrier. Bismuth-ellagic acid is a green phenol-based metal–organic framework whose organic precursor is extracted from natural plants. After encapsulation, the stability, especially the acid-base stability, of amyloglucosidases@bismuth-ellagic acid was enhanced, which remained stable over a wide pH range (2–12) and achieved multiple recycling. By selecting a suitable buffer, bismuth-ellagic acid can encapsulate different types of enzymes and enable interactions between the encapsulated enzymes and cofactors, as well as between multiple enzymes. The green precursor, simple and convenient preparation process provided a versatile strategy for enzymes encapsulation.

关键词： bismuth-ellagic acid     in situ encapsulation     enzyme@MOF biocomposites    

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标题 作者 时间 类型 操作

Optimising the oil phases of aluminium hydrogel-stabilised emulsions for stable, safe and efficient vaccine adjuvant

期刊论文

Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production

期刊论文

The influence of the NCO/OH ratio and the 1,6-hexanediol/dimethylol propionic acid molar ratio on the

Jiao Feng, Qiuhao Lu, Weimin Tan, Kequan Chen, Pingkai Ouyang

期刊论文

Concentrating aqueous hydrochloric acid by multiple-effect membrane distillation

Rongling LIU, Yingjie QIN, Xiaojun LI, Liqiang LIU

期刊论文

高油酸油菜中甘油三酯的组成及结构研究

官梅,陈洪,熊兴华,吕昕,李栒,黄凤洪,官春云

期刊论文

油压极值比与极值比效率

齐茂林

期刊论文

Controlling interstory drift ratio profiles via topology optimization strategies

期刊论文

A methodology of implementing target mixing ratio for asphalt mixture

Yucheng HUANG, Lun JI, Rui WEN, Ming ZHANG

期刊论文

Diagnostic evaluation of plasma aldosterone concentration to plasma renin activity ratio in primary aldosteronism

ZHANG Huilan, WANG Daowen

期刊论文

Enhancing the efficiency of nitrogen removing bacterial population to a wide range of C:N ratio (1.5:

期刊论文

Experimental study of structural damage identification based on modal parameters and decay ratio of acceleration

Zhigen WU, Guohua LIU, Zihua ZHANG

期刊论文

Amino acid promoted hydrogen battery system using Mn-pincer complex for reversible CO hydrogenation toformic acid

期刊论文

Long term performance of recycled concrete beams with different water–cement ratio and recycled aggregate

Jingwei YING; Feiming SU; Shuangren CHEN

期刊论文

Influence of nozzle height to width ratio on ignition and NO

Liutao SUN, Yonghong YAN, Rui SUN, Zhengkang PENG, Chunli XING, Jiangquan WU

期刊论文

Enzyme@bismuth-ellagic acid: a versatile platform for enzyme immobilization with enhanced acid-base stability

期刊论文